You have to be a permanent resident to get to Naturalization, the answer to that is yes in in your case because you did gained your PR through marriage.
You had a green card at one time. This is asking how you got it, because if you got it through marriage to a USC or LPR, you cannot file an I-130 for another spouse until 5 years have passed since your green card was granted. Even if you have since become a citizen.
Yes you can apply now because you have passed the 5 year mark, but be prepared for the interviewer to have a heightened suspicion level, especially if your new wife is originally from the same city and country as you. Even worse if there is evidence that you had a relationship with her before your GC.
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